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Beilstein J. Org. Chem. 2024, 20, 321–330, doi:10.3762/bjoc.20.32
Graphical Abstract
Figure 1: Structures of unguisins.
Figure 2: Chemical structures of unguisin J (1) and unguisin B (2).
Figure 3: Key gHMBC and gCOSY correlations, and NOESY interactions of 1.
Figure 4: Clinker analysis of identified unguisin-encoding BGCs. UngE’ is a methyltransferase that methylates...
Scheme 1: Proposed biosynthesis of unguisins B and J in A. heteromorphus CBS 117.55.
Figure 5: Phylogenetic analysis of A domains extracted from UngA NRPS. The substrate of the A domain is indic...
Figure 6: Phylogenetic analysis of C domains extracted from UngA NRPS. The substrates condensed by each C dom...